Product ID:410, COPPER BASE ALLOYS IN RODS, BARS, (SUP
MSDS Date:08/21/1989
FSC:9525
NIIN:00N031934
MSDS Number: BNZXK

C-S METALS SERVICE INC

7325 WASHINGTON BLVD
BALTIMORE, MD 21227
US

Emergency Phone: 301-796-5661

Info Phone: 301-796-5661

Cage: 86924

C-S METALS SERVICE INC

BALTIMORE, MD 21227 US

Telephone: 301-796-5661

Cage: 86924

TIN

CAS: 7440-31-5

RTECS: XP7320000

Fraction By Weight: 0-11%

OSHA PEL 2 MG/M3

ACGIH TLV: 2 MG/M3

TELLURIUM; (TELLURIUM COMPOUNDS) (SARA III)

CAS: 13494-80-9

RTECS: WY2625000

Fraction By Weight: 0-0.5%

OSHA PEL 0.1 MG/M3

ACGIH TLV: 0.1 MG/M3

IRRIT SKIN/EYES IN BULK FORM. PARTICULATES MAY CAUSE

RTECS: 9999999ZZ

COPPER (SARA III)

CAS: 7440-50-8

RTECS: GL5325000

Fraction By Weight: 45-100%

OSHA PEL 0.1MG/M3 FUME

ACGIH TLV: 0.2MG/M3 FUME

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ZINC (SARA III) (LIMITS GIVEN AS ZN OXIDE)

CAS: 7440-66-6

RTECS: ZG8600000

Fraction By Weight: 0-43%

OSHA PEL 10 MG/M3 TDUST;5RESP

ACGIH TLV: 10 MG/M3

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ALUMINUM (SARA III)

CAS: 7429-90-5

RTECS: BD0330000

Fraction By Weight: 0-15%

OSHA PEL 15MG/M3 DUST;5 RESP

ACGIH TLV: 10MG/M3 DUST;5 FUME

IRON

CAS: 7439-89-6

RTECS: NO4565500

Fraction By Weight: 0-6%

OSHA PEL 10 MG/M3

ACGIH TLV: 5 MG/M3

LEAD (SARA III)

CAS: 7439-92-1

RTECS: OF7525000

Fraction By Weight: 0-5.5%

OSHA PEL 0.05 MG/M3

ACGIH TLV: 0.15 MG/M3 DUST/FUME

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

MANGANESE (SARA III)

CAS: 7439-96-5

RTECS: OO9275000

Fraction By Weight: 0-5%

OSHA PEL (C) 5 MG/M3 DUST

ACGIH TLV: 5 MG/M3 DUST 9293

NICKEL (SARA III)

CAS: 7440-02-0

RTECS: QR5950000

Fraction By Weight: 0-33%

OSHA PEL 1 MG/M3

ACGIH TLV: 1 MG/M3

PHOSPHOROUS (WHITE) (SARA III)

CAS: 7723-14-0

RTECS: TH3500000

Fraction By Weight: 0-0.5%

OSHA PEL 0.1 MG/M3

ACGIH TLV: 0.1 MG/M3

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

SILICON

CAS: 7440-21-3

RTECS: VW0400000

Fraction By Weight: 0-4.5%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST; 9293

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:NOTE:LEAD (CAS #7439-92-1) APPEARS ON
THE NAVY LISTING OF OCCUP REPRO HAZS. SEEK CONSULTATION FROM APPROP
HLTH PROFESSIONALS CONCERNING LATEST HAZ LIST INFO & SAFE HNDLG &
EXPOS REC . UNDER NORM AL HNDLG CONDTNS SOLID ALLOY PRESENTS NO
SIGNIFICANT HLTH HAZ. PROCESSING OF ALLOY BY DUST/FUME (EFTS OF
OVEREXPOS)
Explanation of Carcinogenicity:NICKEL:GROUP 2B (IARC), ANTICIPATED TO
BE A CARCINOGEN (NTP). LEAD:GROUP 2B (IARC).
Effects of Overexposure:HLTH HAZ:PRODUCING OPERATION (GRINDING,
BUFFING, FORGINGS, ETC) MAY RESULT IN POTENTIAL FOR EXPOS TO
AIRBORNE METAL PARTICLATES/FUME. CHRONIC EXPOS TO CU, ZN, PB & MN
MAY CAUSE METAL FUME FEVER. SYMPT INCLUDE FEVER, FATIGUE, DRYNESS
OF THROAT, HEAD & BODY ACHE & CHILLS. OVEREXPOS TO CU & PB MAY
RESULT IN SKIN (SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INGEST:INGEST OF SIGNIFICANT AMOUNTS OF COPPER ALLOYS ARE
UNLIKELY. SEEK MD HELP IF LARGE QUANTITIES OF PRODUCT ARE INGESTED.
INHAL:REMOVE FROM EXPOSURE OF DUST OR FUME IF PRESENT. SEEK MD HELP
IF REQ UIRED. SKIN:WASH THOROUGHLY WITH SOAP AND WATER. EYE:FLUSH
WITH WATER FOR AT LEAST 15 MINUTES. SEEK MD HELP IF REQUIRED.

Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE . NEVER USE
WATER AS AN EXTINGUISHING AGENT AROUND MOLTEN METAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:THERE ARE NO FIRE OR EXPLOSION HAZARDS
WITH THESE ALLOYS. WATER WILL REACT VIOLENTLY WITH ANY MOLTEN
METALS.

Spill Release Procedures:PRODUCT IS A NON HAZARDOUS SOLID. NO SPECIAL
PRECAUTIONS ARE REQUIRED FOR SPILLS OF BULK MATERIAL. SCRAP METAL
CAN BE RECLAIMED FOR REUSE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:WET MATL SHOULD NEVER BE CHARGED INTO
A MOLTEN BATH. TYPICALLY NO SPECIAL PROT REQD BEYOND THAT REQD FOR
PROCESS OPERATION BEING USED.
Other Precautions:EYE PROTECTION SHOULD BE USED WHEN CUTTING, GRINDING,
BUFFING, ETC, OR ANY OTHER PROCESS THAT GENERATES DUST, FUMES,
CHIPS.

Respiratory Protection:WHERE DUST OR FUME LEVELS ARE GREATER THAN THOSE
SPECIFIED IN INGREDIENT SECTION, NIOSH/MSHA APPROVED RESPIRATORY
PROTECTION SHOULD BE USED.
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER USE, ESPECIALLY
BEFORE EATING.
Supplemental Safety and Health
MFR'S TRADE NAME/PART NO:STRIPS, COILS, WIRE, TUBE, INGOTS, CAKE,
CATHODE & SCRAP. EFTS OF OVEREXPOS:& HAIR DISCOLORATION. CHRONIC
EXPOS MAY AFFECT CNS LEADING TO EMOTIONAL DISTURBANCES, GAIT &
BALANC E DIFFICULTIES & PARALYSIS. NICKEL & LEAD HAVE BEEN
IDENTIFIED AS POTENTIAL CANCER CAUSING AGENTS. PROD WILL NOT(ING
12)

HCC:N1
Melt/Freeze Pt:M.P/F.P Text:>1500F,>816
Spec Gravity:7.5-9
Solubility in Water:INSOLUBLE
Appearance and Odor:SILVER/YELLOW TO RED SOLID AT ROOM TEMPERATURE AND
EXHIBITS NO ODOR.

Stability Indicator/Materials to Avoid:YES
MATERIAL MAY REACT WITH ACIDS, BASES OR OXIDIZERS.
Stability Condition to Avoid:ALLOY IS NON HAZARDOUS AT ROOM
TEMPERATURE.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.

Waste Disposal Methods:FOLLOW LOCAL, STATE AND FEDERAL REGULATIONS
REGARDING DISPOSAL.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.